1‐Alkyl‐1H‐imidazole‐Based Dipolar Organic Compounds for Dye‐Sensitized Solar Cells |
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Authors: | Marappan Velusamy Dr Ying‐Chan Hsu Dr Jiann?T Lin Prof?Dr Che‐Wei Chang Chao‐Ping Hsu Prof?Dr |
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Institution: | Institute of Chemistry, Academia Sinica, 115 Nankang, Taipei (Taiwan), Fax: (+886)?2‐27831237 |
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Abstract: | A series of donor–π–acceptor‐type organic dyes based on 1‐alkyl‐1H‐imidazole spacers 1 , 2 , 3 , 4 , 5 have been developed and characterized. The two electron donors are at positions 4 and 5 of the imidazole, while the electron‐accepting cyanoacrylic acid is incorporated at position 2 by a spacer‐containing heteroaromatic rings, such as thiophene and thiazole. Detailed investigation on the relationship between the structure, spectral and electrochemical properties, and performance of DSSC is described here. Dye‐sensitized solar cells (DSSCs) using dyes as the sensitizers exhibit good efficiencies, ranging from 3.06 to 6.35 %, which reached 42–87 % with respect to that of N719‐based device (7.33 %) fabricated and measured under similar conditions. Time‐dependent density functional theory (TDDFT) calculations have been performed on the dyes, and the results show that both electron donors can contribute to electron injection upon photo‐excitation, either directly or indirectly by internal conversion to the lowest excited state. |
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Keywords: | charge transfer donor– acceptor systems dyes photophysics sensitizers |
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