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Physicochemical Properties of Ionic Clathrate Hydrates
Authors:Kyuchul Shin  Jong‐Ho Cha  Yongwon Seo Prof. Dr.  Huen Lee Prof. Dr.
Affiliation:1. Department of Chemical and Biomolecular Engineering (BK21 program) and Graduate School of EEWS, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305‐701 (Republic of Korea), Fax: (+82)?42‐350‐3910;2. Department of Chemical Engineering, Changwon National University, Changwon, Gyeongnam 641‐773 (Republic of Korea)
Abstract:Ionic clathrate hydrates are known to be formed by the enclathration of hydrophobic cations or anions into confined cages and the incorporation of counterions into the water framework. As the ionic clathrate hydrates are considered for their potential applicability in various fields, including those that involve solid electrolytes, gas separation, and gas storage, numerous studies of the ionic clathrate hydrates have been reported. This review concentrates on the physicochemical properties of the ionic clathrate hydrates and the notable characteristics of these materials regarding their potential application are addressed.
Keywords:clathrates  host–  guest systems  hydrates  inclusion compounds  water chemistry
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