| 等离子体条件Cu/SiO2对甲烷偶联的催化作用 |
| |
| 引用本文： | 代斌,宫为民,张秀玲,何仁. 等离子体条件Cu/SiO2对甲烷偶联的催化作用[J]. 催化学报, 2002, 23(4): 297-298 |
| |
| 作者姓名： | 代斌 宫为民 张秀玲 何仁 |
| |
| 作者单位： | Plasma Chemistry Laboratory, Dalian University of Technology, Dalian 116012, Liaoning, China;Department of Chemistry, Shihezi University, Shihezi 832002, Xinjiang, China,Plasma Chemistry Laboratory, Dalian University of Technology, Dalian 116012, Liaoning, China |
| |
| 基金项目： | 国家自然科学基金，29576229， |
| |
| 摘 要： | It has been reported that methane coupling by plasma techniques with catalysts, such as direct current corona discharge with a Sr/La2O3 catalyst[1], dielectric-barrier discharge with zeolites[2] and pulsed corona discharge with metal oxide catalysts[3], give C2 hydrocarbons under atmospheric pressure. But acetylene predominates over other C2 hydrocarbons in the products. Our recent work reported that good results can be obtained for methane coupling under a pulsed corona plasma in the presence of hydrogen[4]. The addition of hydrogen improves the conversion of methane and the yield of C2 hydrocarbons. A methane conversion of 57.1% and a yield of C2 hydrocarbons of 43.4% were obtained at lower power, but acetylene was inevitably the main product. With the introduction of a Ni/γ-Al2O3 catalyst prepared by a cold plasma into the plasma reaction, the distribution of C2 hydrocarbons changed, and the content of C2H4 was 66.1%[5].
|
| 关 键 词： | methane coupling copper supported catalyst hydrogen pulsed corona plasma |
Methane Coupling over Cu/SiO2 Catalyst under a Plasma |
| |
| Abstract: | |
| |
| Keywords: | methane coupling copper supported catalyst hydrogen pulsed corona plasma |
| 本文献已被 万方数据 等数据库收录！ |
|
