Reaction of a stable silylene with tetrahydrofuran |
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| Authors: | B. A. Gostevskii A. I. Albanov I. K. Igumenov N. B. Morozova V. I. Rakhlin |
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| Affiliation: | (1) Favorskii Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, ul. Favorskogo 1, Irkutsk, 664033, Russia;(2) Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia |
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| Abstract: | Reduction of 1,3-di-tert-butyl-2,2-dichloro-2,3-dihydro-1H-1,3,2-diazasilole with metallic potassium gave, instead of a stable silylene, 1,3-di-tert-butyl-2,3-dihydro-1H-1,3,2λ2-diazasilylolene, a product of insertion of the latter into the carbon-oxygen bond of tetrahydrofuran, 1,4-di-tert-butyl-6-oxa-1,4-diaza-5-silaspiro[4,5]dec-2-ene. |
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