| 双-(二烷基膦)乙烷合铂配合物的13C NMR研究 |
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| 引用本文： | 张安将 姜琼忠. 双-(二烷基膦)乙烷合铂配合物的13C NMR研究[J]. 波谱学杂志, 1991, 8(2): 215-220 |
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| 作者姓名： | 张安将 姜琼忠 |
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| 作者单位： | 1. 华西医科大学药学院 成都;2. 中科院成都有机化学研究所 成都 |
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| 摘 要： | 本文报道Cis-Pt(disphos)X2系列化合物的13C NMR研究。发现配体X、取代基R对桥环碳(C1)化学位移有明显的影响;并证实了某些化合物象异构体的存在,还对构象特性进行了讨论。
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| 关 键 词： | 核磁共振 构象 配体 |
| 收稿时间： | 1990-07-03 |
13C NMR STUDY OF THE PLATINUM (Ⅱ) COMPLEXES OF BIS (DIALKYLPHOSPHINO) ETHANE |
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| Zhang An Jiang,Jiang Qiongzhong,Zhang Liangfu. 13C NMR STUDY OF THE PLATINUM (Ⅱ) COMPLEXES OF BIS (DIALKYLPHOSPHINO) ETHANE[J]. Chinese Journal of Magnetic Resonance, 1991, 8(2): 215-220 |
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| Authors: | Zhang An Jiang Jiang Qiongzhong Zhang Liangfu |
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| Affiliation: | 1. School of Phannacy, West China University of Medical Sciences, Chengdu;2. Chengdu Institute of Organic Chemistry, Acadcmia Science |
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| Abstract: | 13C NMR of a series of cis-Pt (diphos) X2 complexes was studied. The results showed that X ligand and R alkyl have considerable effect on the chemical shift of bridge carbon (C1). The existance of conformational isomers of some compounds was confirmed and the conformational characteristics of platinum complexes was discussed. |
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| Keywords: | 13C NMR Cis-Pt (diphos) X2 Conformation |
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