Oxidation of N-substituted dopamine derivatives: irreversible formation of a spirocyclic product |
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Authors: | Land Edward J Perona Almudena Ramsden Christopher A Riley Patrick A |
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Institution: | School of Chemistry and Physics, Keele University, Keele, Staffordshire, UKST5 5BG. |
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Abstract: | Oxidation of amide, urea and guanidinium derivatives of dopamine gives relatively stable ortho-quinones whereas oxidation of corresponding thioamide and amidinium derivatives rapidly and quantitatively gives novel bicyclic and spirocyclic products formed via the corresponding ortho-quinone. |
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