| Synthesis,Crystal Structure and Luminescent Property of a New Copper(Ⅰ) Iodide Complex Based on 3,5-Dimethyl-4-amino-triazole |
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| 引用本文： | 赵振国,吴小园,张其胜,谢奕明,余荣民,卢灿忠.Synthesis,Crystal Structure and Luminescent Property of a New Copper(Ⅰ) Iodide Complex Based on 3,5-Dimethyl-4-amino-triazole[J].结构化学,2010(2):245-249. |
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| 作者姓名： | 赵振国 吴小园 张其胜 谢奕明 余荣民 卢灿忠 |
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| 作者单位： | State;Laboratory;Structural;Chemistry;Fujian;Institute;Research;Structure;Matter;Chinese;Academy;Sciences; |
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| 基金项目： | supported by the National Natural Science Foundation of China (20873150, 20821061, and 50772113);;Chinese Academy of Sciences (KJCX2-YW-M05);;the Natural Science Foundation of Fujian Province (2006F3135, 2006F3141, 2007HZ0001-1);;the Fund of Fujian Key Laboratory of Nanomaterials (2006L2005) |
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| 摘 要： | The title compound,Cu4I4(C4H8N4)4],has been synthesized and characterized by single-crystal X-ray diffraction analysis.It crystallizes in monoclinic,space group Pbca,with a=18.1851(10),b=9.3697(5),c=19.8034(10),V=3374.3(3)3,C16H32Cu4I4N16,Mr=1210.34,Z=4,Dc=2.383 g/cm3,μ=6.183 mm-1,F(000)=2272,S=1.032,the final R=0.0309 and wR=0.1180 for 3854 observer reflections(I2σ(I)).The structure of the title compound consists of tetranuclear copper cluster units bridged by the halogen atoms with the 3,5-dimethyl-4-aminotriazole ligands coordinated to the metal ions through the triazole nitrogen atoms.The luminescent property of 1 was also studied.
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| 关 键 词： | 晶体结构 铜（Ⅰ） 发光性能 二甲基 三唑基 合成 复合物 标题化合物 |
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