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Quantal master equation valid for any time scale
Authors:Natsuki Hashitsumae  Fumiaki Shibata  Mayumi Shing¯u
Institution:(1) Department of Physics, Faculty of Science, Ochanomizu University, Tokyo, Japan
Abstract:A new memoryless expression for the equation of motion for the reduced density matrix is derived. It is equivalent to that proposed by Tokuyama and Mori, but has a more convenient form for the application of the perturbational expansion method. The master equation derived from this form of equation in the first Born approximation is applied to two examples, the Brownian motion of a quantal oscillator and that of a spin. In both examples the master equation is rewritten into the coherent-state representation. A comparison is made with the stochastic theory of the spectral line shape given by Kubo, and it is shown that this theory of the line shape can be incorporated into the framework of the present theory.
Keywords:Statistical mechanics  damping theory  master equation  Brownian motion  quantal oscillator  spin
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