Kinetics of oxidation of methanol by chlorine dioxide |
| |
| Authors: | C B Sharma |
| |
| Institution: | (1) Chemical Laboratories, D. N. College, 250002 Meerut, India |
| |
| Abstract: | The kinetics of oxidation of methanol by chlorine dioxide has been investigated at 35 °C. The reaction is first order with respect to both substrate and chlorine dioxide. Molecular chlorine dioxide is the principal oxidant. The influence of various factors, e.g. ionic strength, inorganic salts, D2O and temperature on the initial rate has been studied. The activation parameters have been calculated and a mechanism involving hydride abstraction has been suggested.
                      35 °C.    , .  .     , . ,  , D2O , . ,  .
|
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
