Temperature controlled ionic liquid dispersive liquid phase microextraction was developed for the enriching three carbamate pesticides. 1-Hexyl-3-methylimidazolium hexafluorophosphate was used as the extractant. The detection limits for isoprocarb, diethofencarb, fenothiocarb are 0.91, 0.45, 1.40 μgL-1. Real-world environmental water samples analysis indicated that it was a viable alternative to existing methods.