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Study on the Forming Mechanism and Preparation of Different Morphology of Barium Carbonate Crystals with Diethyl Carbonate as Raw Material
Authors:WANG Li-Na  HUO Ji-Chuan  LIU Ming  LIU Shu-Xin  LEI Yong-Lin
Institution:1. Institute of Applied Chemistry, Southwest University of Science and Technology, Mianyang 621010, China
2. Department of Chemistry and Chemical Engineering, Mianvang Normal University, Mianyang 621010, China
Abstract:Different morphologies of BaCO3 crystals with dendritic structure,spinous sphere structure,and spike-,flower-and rod-like structures were prepared with(C2H5)2CO3 and BaCl2.2H2O as raw materials by homogeneous precipitation method.The crystals have been characterized by SEM,FT-IR and XRD,indicating that the different morphology of BaCO3 crystals belongs to the orthorhombic crystal system with uniform distribution and integral shapes.The effect of reaction conditions and the possible formation mechanism on the morphology of BaCO3 crystals have been discussed.
Keywords:diethyl carbonate  barium carbonate  morphology
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