| Synthesis,Crystal Structure and Luminescence of a Novel Cadmium（Ⅱ） Coordination Polymer with 5-Connected nov Net |
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| 作者姓名： | WANG Peng-Fei WU Xiao-Shuo WU Qiu-Yan WANG Xin |
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| 作者单位： | Center of Chemical Materials and Engineering Experiment, Department of Chemistry and FoodScience, Chizhou College, Chizhou 247000, China |
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| 基金项目： | the National Natural Science Foundation of China，the Natural Science Foundation of Anhui Province University，the Chizhou College，the Materials Key Subject of Chizhou College |
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| 摘 要： | A novel interesting coordination polymer,[Cd(HSSA)(2-bimb)2].3H2O(1,H3SSA = 5-sulfosalicylic acid,2-bimb = 1,2-bis(imidazol-1-ylmethyl)-benzene),has been synthesized and structurally characterized.Compound 1 crystallizes in the monoclinic system,space group P21/n with a = 10.8653(10),b = 19.4100(17),c = 17.4414(17) ,β = 91.944(2)°,V = 3676.2(6) 3,Z = 4,C35H38CdN8O9S,Mr = 859.19,Dc = 1.552 g/cm3,μ = 0.717 mm-1,S = 0.999,F(000) = 1760,R = 0.0531 and wR = 0.1078.The compound features a rare three-dimensional(3D) 5-connected nov topology.In addition,compound 1 exhibits strong photoluminescent emission at room temperature.
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| 关 键 词： | 配位聚合物 晶体结构 合成 发光 镉 磺基水杨酸 化合物 HSSA |
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