Synthesis of phosphate-type fluorocarbon-hydrocarbon hybrid surfactants and their adsorption onto calcium hydroxyapatite |
| |
| Authors: | Haruhiko Miyazawa Yuki Ohkubo Norio Yoshino |
| |
| Institution: | a Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601, Japan
b Institute of Colloid and Interface Science, Tokyo University of Science, 1-3 Kagurazaka, Shinjuku, Tokyo 162-8601, Japan |
| |
| Abstract: | Five novel phosphate-type hybrid surfactants, CmF2m+1C6H4CHOPO2(OC6H5)Na]CnH2n+1 (FmPHnPPhNa: m = 4, 6, 8; n = 3, 5), have been synthesized. When compared with sulfate-type hybrid surfactants, CmF2m+1C6H4CH(OSO3Na)CnH2n+1 (C6H4 = p-phenylene), the new hybrid surfactants were found to have comparable abilities to lower the surface tension of water. The critical micelle concentrations of FmPHnPPhNa followed Klevens’ rule and their occupied areas per molecule increased with increasing m and n. Calcium hydroxyapatite (CaHAp) pellets modified with FmPH3PPhNa gave high hydro and lipophobic surfaces. The hybrid surfactants are expected to be useful as new dental reagents for oral hygiene. |
| |
| Keywords: | Hybrid surfactant Phosphate-type Fluorocarbon Calcium hydroxyapatite Human teeth Hydro and lipophobic surface Plaque-controlling surface |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
