|
|||||
|
|
A mild ring opening fluorination of epoxide with ionic liquid 1-ethyl-3-methylimidazorium oligo hydrogenfluoride (EMIMF(HF)2.3) |
|
| Authors: | Hideaki Yoshino Seijiro Matsubara Koichiro Oshima Rika Hagiwara |
| Affiliation: | a Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Kyoutodaigaku-Katsura, Nishikyo, Kyoto 615-8510, Japan b Department of Fundamental Energy Science, Graduate School of Energy Science, Kyoto University, Yoshida hon-machi, Sakyo, Kyoto 606-8501, Japan |
| Abstract: | Ring opening fluorination of epoxides with hydrogen fluoride in ionic liquid 1-ethyl-3-methylimidazorium oligo hydrogenfluoride EMIMF(HF)2.3 was demonstrated. This ionic liquid released hydrogen fluoride graduately to make mild conditions without oligomerization of epoxides. |
| Keywords: | Fluorohydrin Epoxide ring opening Hydrogen fluoride Ionic liquid |
| 本文献已被 ScienceDirect 等数据库收录！ | |