| The Mechanism on Cyclization, Debenzylation and Oxidation of 1-[1-（Benzyloxy）-3-methylnaphthalen-4-yloxy]propan-2-one |
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| 引用本文： | Shi Liang HUANG Yi LUO Zhi Shu HUANG Xian Zhang BU Pei Qing LIU Lin MA Yue Ming LI Albert S. C. CHAN Lian Quan GU. The Mechanism on Cyclization, Debenzylation and Oxidation of 1-[1-（Benzyloxy）-3-methylnaphthalen-4-yloxy]propan-2-one[J]. 中国化学快报, 2006, 17(6): 769-772 |
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| 作者姓名： | Shi Liang HUANG Yi LUO Zhi Shu HUANG Xian Zhang BU Pei Qing LIU Lin MA Yue Ming LI Albert S. C. CHAN Lian Quan GU |
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| 作者单位： | [1]School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275 [2]School of Pharmaceutical Science, Sun Yat-Sen University, Guangzhou 510275 [3]Department of Applied Bioiogy ＆ Chemical Technology, The Hong Kong Polytechnic University, Kowloon, Hong Kong |
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| 基金项目： | 中国科学院资助项目;广东省博士启动基金 |
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| 摘 要： | Mansonone compounds represent a series of naturally occurring o-quinones mainly isolated from the heartwood of Mansonia Altissima1 and Ulmus Glabra2. Mansonone F contained oxaphenalene skeleton which was a relatively novel structure and rarely existed in …
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| 关 键 词： | 环化作用 脱苄基作用 氧化 二氧化硒 [2 3] 单键转移重整 1-[1-（苄氧基）-3-甲基萘基-氧]丙酮 |
| 收稿时间： | 2005-12-16 |
The Mechanism on Cyclization, Debenzylation and Oxidation of 1-[1-(Benzyloxy)-3-methylnaphthalen-4-yloxy]propan-2-one |
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| Shi Liang HUANG,Yi LUO,Zhi Shu HUANG,Xian Zhang BU,Pei Qing LIU,Lin MA,Yue Ming LI,Albert S. C. CHAN,Lian Quan GU. The Mechanism on Cyclization, Debenzylation and Oxidation of 1-[1-(Benzyloxy)-3-methylnaphthalen-4-yloxy]propan-2-one[J]. Chinese Chemical Letters, 2006, 17(6): 769-772 |
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| Authors: | Shi Liang HUANG Yi LUO Zhi Shu HUANG Xian Zhang BU Pei Qing LIU Lin MA Yue Ming LI Albert S. C. CHAN Lian Quan GU |
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| Abstract: | 1-[1-(Benzyloxy)-3-methylnaphthalen-4-yloxy]propan-2-one (1a) took place a cycli- zation, debenzylation and oxidation to form 9-substitued benzo[de]chromene-7,8-dione (2a) and 5-benzyl-9-substitued benzo[de]chromene-7,8-dione (3a). The mechanisms for these reactions were discussed. |
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| Keywords: | Mansonone F cyclization selenium dioxide [2 3]sigmatropic rearrangement. |
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