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一种新型聚酯醚砜热致液晶高分子的合成与表征
引用本文:倪玉山,王云辉,李光,金晓明. 一种新型聚酯醚砜热致液晶高分子的合成与表征[J]. 高分子学报, 1995, 0(1): 14-17
作者姓名:倪玉山  王云辉  李光  金晓明
作者单位:中国科学院长春应用化学研究所
摘    要:由对苯二甲酸、4,4'-双(4-羟基苯氧基)二苯枫和对羟基苯甲酸合成了具有液晶特性的一种新型聚酯醚砜.从反应介质预聚合和后聚合等因素讨论了提高聚合物粘度的途径,以DSC、偏光显微镜和X-线衍射仪等方法表征了其液晶特性.

关 键 词:热致液晶高分子,聚酯酸砜,4,4'-双(4-羟基苯氧基)二苯砜
收稿时间:1992-04-25

SYNTHESIS AND CHARACTERIZATION OF A NEW THERMOTROPIC LIQUID CRYSTALLINE POLYESTER-ETHER SULFONE
NI Yu-shan,WANG Yun-hui,LI Guang,JIN Xiao-ming. SYNTHESIS AND CHARACTERIZATION OF A NEW THERMOTROPIC LIQUID CRYSTALLINE POLYESTER-ETHER SULFONE[J]. Acta Polymerica Sinica, 1995, 0(1): 14-17
Authors:NI Yu-shan  WANG Yun-hui  LI Guang  JIN Xiao-ming
Affiliation:Changchun Institute of Applied Chemistry; Academia Sinica; Changchun 130022
Abstract:new aromatic polyester-ether sulfone TLCP was prepared from 4,4 bis(4-hydroxy phenoxy) diphenyl sulfone, terephthalic acid and p-hydroxybenzoic acid. Some factors which affected melting viscosity of the polymer, such as prepolymerization reaction medium and post-polymerization reaction, etc, were discussed.The liquid crystalline properties were characterized by DSC, polarizing microscope with a hot stage and X-ray diffractometer.
Keywords:Thermotropic Liquid crystalline polymer   4  4'-bis(4-hydroxy phenoxy)diphenyl sulfone polyester-ether sulfone
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