Synthesis and structural investigation of a new cadmium cyclohexaphosphate Cd[3,4-(CH3)2C6H5NH3]4P6O18·6H2O |
| |
Authors: | S. Abid M. Rzaigui |
| |
Affiliation: | (1) Laboratoire de Chimie des Materiaux, 7021 Zarzouna, Bizerte, Tunisie |
| |
Abstract: | Single crystals of a new cyclohexaphosphate, are synthesised and investigated by X-ray diffraction. This compound crystallizes in the triclinic system with the space group P-1 and cell parameters a=7.773(4), b=9.238(3), c=18.532(7) Å, α=88.57(3), β=88.10(4), γ=67.35(4)°, Z=1 and V=1227(1) Å3. The three-dimensional network is built up from parallel (0 0 1) layers of [CdP6O18(H2O)6]4− between which the organic molecules are inserted. The Cd atoms, in 1(a) sites, adopt an octahedral coordination. The 3,4-xylidinium cations exercise an electrostatic interaction on the inorganic anion and establish strong H-bonds with their oxygen atoms. |
| |
Keywords: | Cyclophosphate Organic– inorganic compound Chemical synthesis X-ray diffraction Structure Layer. |
本文献已被 SpringerLink 等数据库收录! |
|