| 尾式卟啉铁一氧化碳配合物性质研究 |
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| 引用本文： | 曹锡章,牟西海. 尾式卟啉铁一氧化碳配合物性质研究[J]. 高等学校化学学报, 1986, 7(1): 7 |
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| 作者姓名： | 曹锡章 牟西海 |
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| 作者单位： | 吉林大学化学系 |
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| 摘 要： | 一种新型的第五配位基为叔胺的尾式卟啉铁(间-(邻-(4-二乙胺基丁酰胺基(苯基)三苯基卟啉合铁(Ⅱ),meso-MDBPTPPFe(Ⅱ))同CO反应生成配合物,用分光光度法测定了配合物的平衡常数,解释了可见紫外光谱的位移现象,用红外差谱方法测得CO的伸缩振动频率是1961cm-1。
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| 收稿时间： | 1984-08-27 |
Studies on Carbon Monoxide Complex of a New Tailed Porphyriniron |
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| Cao Xizhang,Mu Xihai. Studies on Carbon Monoxide Complex of a New Tailed Porphyriniron[J]. Chemical Research In Chinese Universities, 1986, 7(1): 7 |
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| Authors: | Cao Xizhang Mu Xihai |
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| Affiliation: | Department of Chemistry, Jilin University, Changchun |
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| Abstract: | The carbon monoxide adduct of Fe complex of meso-mono[o-(4-dietheyla-mino) butyramidophenyl] triphenylporphyrin (tailed porphyrin, meso-MDBPTPP) is reported. The equilibrium constant of the adduct was measured by spectrophoto-metric method and the COvibration was obtained by using differential spectrum technique. Experimental results demonstrate that the fifth ligand affects the equilibrium constant dramatically. |
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