Synthesis and Structural Characterization of a Layered Tin(II) Phosphate, [Sn2(PO4)2][C2N2H10]·H2O |
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| Authors: | Srinivasan Natarajan Anthony K. Cheetham |
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| Affiliation: | Materials Research Laboratory, University of California, Santa Barbara, California, 93116, f1 |
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| Abstract: | A new layered tin(II) phosphate [Sn2(PO4)2]2−[C2N2H10]2+·H2O was synthesized by hydrothermal technique. It crystallizes in monoclinic space groupP21/c(No. 14) with lattice parametersa=9.4112(1) Å;b=8.5998(1) Å;c=15.9921(2) Å;β=100.009(1)°;V=1274.61(2);Z=4;R=2.06%;Rw=2.17%. The structure consists of inorganic layers, comprising a network of strictly alternating SnO3and PO4moieties and held together by strong hydrogen bonding between the layers. Protonated ethylenediamine and water molecules are trapped between the layers. |
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