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Effects of flammability characteristics of steam inerting to solution of acetone in water
Authors:C -H Lin  Y -M Chang  J -C Lee  S -Y Lin  C -M Shu
Institution:(1) Doctoral Program, Graduate School of Engineering Science and Technology, National Yunlin University of Science and Technology (NYUST), 123, University Rd., Sec. 3, Douliou, Yunlin, Taiwan, 64002, Republic of China;(2) Department of Safety, Health, and Environmental Engineering, NYUST, 123, University Rd., Sec. 3, Douliou, Yunlin, Taiwan, 64002, Republic of China
Abstract:Preventing accidental explosions of flammable liquid/gas mixtures is very important. As far as flammability characteristics are concerned, we simulated the effects of inert liquid/gas, which was filled with reactors, vessels, or closed space, employed in the chemical process industries. The inert liquid/gas (H2O) weakened the oxygen concentration and reduced solvent vapor concentration in a 20-L-Apparatus. This study investigated the flammability characteristics of acetone/water solutions (100/0, 75/25, 50/50, and 25/75 vol.%) that are controlled at a temperature of 150°C and pressures of 101/202 kPa, respectively. The flammability parameters included flammability limits (LEL and UEL), maximum explosion pressure (P max), maximum explosion pressure rise ((dP dt −1)max), and vapor deflagration index (K g). The results of a series of experimental tests showed that UEL, P max, and K g all decreased with steam rising under the experimental conditions. The results can be applied to process safety design/operation for identifying whether the inert liquid/gas (H2O) content has any substantial effects in reducing the fire and explosion hazard of the solution of interest.
Keywords:acetone/water solutions  explosion accidents  flammability parameters  inert liquid/gas (H2O)  20-L-Apparatus
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