| 磺化含芴聚醚醚酮酮的合成及与八苯胺基POSS的杂化 |
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| 引用本文： | 李龙,刘佰军,刘思远,姜振华.磺化含芴聚醚醚酮酮的合成及与八苯胺基POSS的杂化[J].高等学校化学学报,2012,33(6):1121-1123. |
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| 作者姓名： | 李龙 刘佰军 刘思远 姜振华 |
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| 作者单位： | 吉林大学化学学院, 麦克德尔米德实验室, 长春 130012 |
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| 基金项目： | 国家自然科学基金，吉林省科技厅国际合作项目 |
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| 摘 要： | 设计并合成了一种新型的含有芴结构的磺化聚醚醚酮酮, 并将八苯胺-POSS引入聚合物中, 制备出一类具有酸-碱相互作用的复合型质子交换膜, 并对其性能进行了研究.
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| 关 键 词： | 质子交换膜 聚芳醚酮 聚倍半硅氧烷 杂化 |
| 收稿时间： | 2012-01-09 |
Synthesis of Sulfonated Fluorenyl-containing PEEKK and Its AMPH-POSS Hybrid Membranes |
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| LI Long
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LIU Bai-Jun
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LIU Si-Yuan
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JIANG Zhen-Hua.Synthesis of Sulfonated Fluorenyl-containing PEEKK and Its AMPH-POSS Hybrid Membranes[J].Chemical Research In Chinese Universities,2012,33(6):1121-1123. |
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| Authors: | LI Long LIU Bai-Jun LIU Si-Yuan JIANG Zhen-Hua |
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| Institution: | Alan G. McDiarmid Institute, College of Chemistry, Jilin University, Changchun 130012, China |
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| Abstract: | Fluorenyl-containing sulfonated poly(ether ether ketone ketone) was synthesized through a post-sulfonation method as the matrix,and AMPH-POSSoctaminophenyl polyhedral oligomeric silsesquioxane] was selected as filler to form acid-base enhanced proton exchange membranes by solution casting.The microstructure and some basic properties were investigated.The filler was well dispersed in the polymer matrix.The hybrid membranes exhibited improved swelling stability,selectivity and methanol permerbilities. |
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| Keywords: | Proton exchange membrane Poly(arylene ether ketone)s Octaminophenyl polyhedral oligomeric silsesquioxane(POSS) Hybrid |
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