A 3,4-connected beryllium phosphite framework containing 24-ring channels with a very low density |
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Authors: | Luo Xiuchao Luo Daibing Zeng Hongmei Gong Maochu Chen Yaoqiang Lin Zhien |
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Affiliation: | College of Chemistry, Sichuan University, Chengdu 610064, People's Republic of China. |
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Abstract: | A new three-dimensional open-framework beryllium phosphite with honeycomb-like channels has been prepared under solvothermal conditions. The alternation of a 24-ring window and a 30-ring window along its extra-large channel is unprecedented in open-framework materials. The compound has a very low density of 1.369 g cm(-3) by integrating an extra-large-pore, interrupted 3,4-connected framework and lightweight beryllium metal in its crystalline structure. |
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