| 冲击波处理结晶MgO的ESR研究及对丁烯异构化的影响 |
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| 引用本文： | 张菊,徐康.冲击波处理结晶MgO的ESR研究及对丁烯异构化的影响[J].高等学校化学学报,1996,17(4):635-637. |
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| 作者姓名： | 张菊 徐康 |
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| 作者单位： | 杭州大学催化研究所，中国科学院兰州化学物理研究所 |
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| 基金项目： | 国家自然科学基金,浙江省自然科学基金 |
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| 摘 要： | 冲击波处理结晶ＭｇＯ的ＥＳＲ研究及对丁烯异构化的影响张菊，郑小明，倪哲民徐康，杨廷录，刘建军（杭州大学催化研究所，杭州，３１００２８）（中国科学院兰州化学物理研究所）关键词冲击波，结晶ＭｇＯ，ＥＳＲ，丁烯异构化由爆炸在凝聚态物质中产生的冲击波是一种以...
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| 关 键 词： | 冲击波 ESR 丁烯 异构化 氧化镁 催化剂活性 |
Studies on ESR Spectra of Mgo Crystal Treated by Shock Wave and Its Activity for Isomerization of Butene-1 |
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| ZHANG Ju,ZHENG Xiao-Ming,NI Zhe-Min.Studies on ESR Spectra of Mgo Crystal Treated by Shock Wave and Its Activity for Isomerization of Butene-1[J].Chemical Research In Chinese Universities,1996,17(4):635-637. |
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| Authors: | ZHANG Ju ZHENG Xiao-Ming NI Zhe-Min |
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| Abstract: | After being treated by shock wave,F color centers are formed on MgO crystaland some new signals of free radical appear in the ESR spectrum,The results of isomerization of butene-1 showed that the MgO crystal treated by shock wave exhibits a higherconversion of butene-1 and higher yield of cis-butene due to an increase in defects. |
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| Keywords: | Shock wave MgO crystal ESR Isomerization of butene-1 |
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