<Emphasis Type="Italic">N</Emphasis>-(2-Azidoethyl) derivatives of methylenebis(1-oxytriaz-1-ene 2-oxides) |
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| Authors: | G A Smirnov P B Gordeev S V Nikitin G V Pokhvisneva T V Ternikova I M Chistokhvalov O A Luk’yanov |
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| Institution: | 1.N. D. Zelinsky Institute of Organic Chemistry,Russian Academy of Sciences,Moscow,Russian Federation;2.D. Mendeleev University of Chemical Technology of Russia,Moscow,Russian Federation |
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| Abstract: | A method for synthesizing new compounds capable of releasing NO within living organisms, namely, 2-azidoethyl derivatives of methylenebis(1-oxytriaz-1-ene 2-oxides) bearing one or few 2-azidoethyl moieties, was developed. The synthesis involves nucleophilic substitution of the bromine atoms of the parent 2-bromoethyl derivatives of methylenebis(1-oxytriaz-1-ene 2-oxides) with the azide group. Some of the synthesized compounds are of interest as promising energetic materials. |
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