Reaction of CH-acidic phosphorylated acetamidines with chlorotrimethylsilane |
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Authors: | V. E. Shishkin E. V. Mednikov M. A. Shevchenko O. V. Anishchenko Yu. V. Popov E. V. Gurba B. D. Emenka |
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Affiliation: | 1.Volgograd State Technical University,Volgograd,Russia |
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Abstract: | A reaction of sodium derivatives of C-phosphorylated acetamidines with clorotrimethylsilane was investigated. The reaction proceeds selectively with the formation of the acetamidines silylated derivatives. Using the CH-acid properties of C-phosphorylated acetamidines a convenient method was developed for the synthesis of a new type of organophosphorus-silicon amidines. |
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