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Reaction of CH-acidic phosphorylated acetamidines with chlorotrimethylsilane
Authors:V. E. Shishkin  E. V. Mednikov  M. A. Shevchenko  O. V. Anishchenko  Yu. V. Popov  E. V. Gurba  B. D. Emenka
Affiliation:1.Volgograd State Technical University,Volgograd,Russia
Abstract:A reaction of sodium derivatives of C-phosphorylated acetamidines with clorotrimethylsilane was investigated. The reaction proceeds selectively with the formation of the acetamidines silylated derivatives. Using the CH-acid properties of C-phosphorylated acetamidines a convenient method was developed for the synthesis of a new type of organophosphorus-silicon amidines.
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