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Debundling, selection and release of SWNTs using fluorene-based photocleavable polymers
Authors:Lemasson Fabien  Tittmann Jana  Hennrich Frank  Stürzl Ninette  Malik Sharali  Kappes Manfred M  Mayor Marcel
Institution:Karlsruhe Institute of Technology (KIT), Institute for Nanotechnology, P.O. Box 3640, D-76021 Karlsruhe, Germany.
Abstract:Photocleavable polymers based on 9,9-dialkylfluorene backbone and o-nitrobenzylether were designed and synthesized to obtain stable (n,m) enriched suspensions of semiconducting SWNTs in toluene. Photoirradiation of the suspensions triggered the precipitation of the SWNTs and TEM images indicate close packing of SWNTs pointing at partial removal of the coating polymer.
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