Transfer Hydrogenation of Ketones Catalyzed by 1-Alkylbenzimidazole Ruthenium(II) Complexes |
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| Authors: | İsmail Özdemir Neslihan Şahin Bekir Çetinkaya |
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| Institution: | 1.Department of Chemistry,In?nü University Faculty Science and Art,Malatya,Turkey;2.Department of Chemistry,Cumhuriyet University Faculty Science and Art,Sivas,Turkey;3.Department of Chemistry,Ege University,Bornova-?zmir,Turkey |
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| Abstract: | Summary. Six RuCl2(1-alkylbenzimidazole)(p-cymene)] complexes have been prepared and the new compounds characterized by C, H, N analyses, 1H NMR, and 13C NMR. The reduction of ketones to alcohols via transfer hydrogenation was achieved with catalytic amounts of the complexes in the presence of t-BuOK. |
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| Keywords: | , Ruthenium, Benzimidazole ligands, Transfer hydrogenation, Homogeneous catalysis, |
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