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Positive photocatalysis of a Diels-Alder reaction by quenching of excited naphthalene-indole charge-transfer complex with cyclohexadiene
Authors:Gonzalez-Béjar María  Stiriba Salah-Eddine  Miranda Miguel A  Pérez-Prieto Julia
Affiliation:Dep. Q. OrgAnica/ICMOL, Universidad de Valencia, Polígono La Coma, 46980 Paterna, Valencia, Spain.
Abstract:[reaction: see text] Naphthalene photo-catalyzes formation of cyclohexadiene-indole cycloadducts in a wavelength-dependent process. Steady-state irradiation and time-resolved fluorescence studies agree well with NP-InH ground-state charge transfer (CT) complexes as the key species responsible for the photo-catalyzed process.
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