Positive photocatalysis of a Diels-Alder reaction by quenching of excited naphthalene-indole charge-transfer complex with cyclohexadiene |
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Authors: | Gonzalez-Béjar María Stiriba Salah-Eddine Miranda Miguel A Pérez-Prieto Julia |
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Affiliation: | Dep. Q. OrgAnica/ICMOL, Universidad de Valencia, Polígono La Coma, 46980 Paterna, Valencia, Spain. |
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Abstract: | [reaction: see text] Naphthalene photo-catalyzes formation of cyclohexadiene-indole cycloadducts in a wavelength-dependent process. Steady-state irradiation and time-resolved fluorescence studies agree well with NP-InH ground-state charge transfer (CT) complexes as the key species responsible for the photo-catalyzed process. |
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