Calorimetrictitration experiment modelled by equilibrium of 2:1 and 1:1 complexes

The analysis of the calorimetric continuous titration experiment is presented. The proposed method is basing on the collection of larger number of experimental data points than could be obtained from the classical isothermal titration calorimetry experiment. After the deconvolution procedure resulting in the correction for the calorimeter time response the pure power effect signal could be obtained. The collected data enable the detailed analysis of the closely populated 2:1 and 1:1 weak complexes.