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Non-stoichiometric magnetite and maghemite in the mature teeth of the chitonAcanthopleura hirtosa
Authors:T. G. St. Pierre  L. A. Evans  J. Webb
Affiliation:(1) School of Mathematical and Physical Sciences, Murdoch University, 6150 Perth, W.A., Australia
Abstract:Mature radula pieces from the chitonAcanthopleura hirtosa were studied using Mössbauer spectroscopy. The magnetite present in the radulae was found to have a distribution of Verwey transition temperatures in the range 85–100K. It was deduced that the magnetite was non-stoichiometric with an average formula Fe2.98O3. About 10% of the Fe in the radulae was in the form of maghemite and about 19% was in the form of paramagnetic or superparamagnetic phases.
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