Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts |
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| Authors: | Rios Ramon Pericàs Miquel A Moyano Albert Maestro Miguel A Mahía José |
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| Affiliation: | Unitat de Recerca en Síntesi Asimètrica, Departament de Química Orgànica, Facultat de Química, Universitat de Barcelona, Martí i Franquès, 1-11, 08028 Barcelona, Spain. |
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| Abstract: | [reaction: see text] An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene. |
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