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双取代单酰胺与硝酸铀酰萃合物的制备与表征
引用本文:孙国新,于涛,崔玉,张振伟,李业新. 双取代单酰胺与硝酸铀酰萃合物的制备与表征[J]. 无机化学学报, 2005, 21(3): 363-368
作者姓名:孙国新  于涛  崔玉  张振伟  李业新
作者单位:济南大学化学化工学院,济南,250022
基金项目:国家自然科学基金(No.20301008),山东省自然科学基金(No.Q2003B01)资助项目
摘    要:合成了系列双取代单酰胺萃取剂,利用萃取方法获得了与硝酸铀酰的萃合物。利用元素分析、红外光谱、1H NMR和13C NMR对萃合物进行了表征。结合实验数据初步探讨了萃合物的结构、萃取剂的结构与性能以及萃取体系的三相等问题。

关 键 词:单酰胺; 硝酸铀酰; 萃合物; 结构; 表征
文章编号:1001-4861(2005)03-0363-06
收稿时间:2004-07-12
修稿时间:2004-07-12

Preparation and Characterization of Extracted Species of Uranyl Nitrate with Disubstituted Monoamides
SUN Guo-Xin,YU Tao,CUI Yu,ZHANG Zhen-Wei and LI Ye-Xin. Preparation and Characterization of Extracted Species of Uranyl Nitrate with Disubstituted Monoamides[J]. Chinese Journal of Inorganic Chemistry, 2005, 21(3): 363-368
Authors:SUN Guo-Xin  YU Tao  CUI Yu  ZHANG Zhen-Wei  LI Ye-Xin
Affiliation:Institute of Chemistry and Chemical Engineering, Jinan University, Jinan 250022,Institute of Chemistry and Chemical Engineering, Jinan University, Jinan 250022,Institute of Chemistry and Chemical Engineering, Jinan University, Jinan 250022,Institute of Chemistry and Chemical Engineering, Jinan University, Jinan 250022 and Institute of Chemistry and Chemical Engineering, Jinan University, Jinan 250022
Abstract:A series of disubstituted monoamides extractants were synthesized and their extracted species with uranyl nitrate were obtained by extraction method. The foregoing extracted species were characterized by elemental analysis, infrared spectra, 1H NMR and 13C NMR. The structure of the extracted species, the relationship between extractant structure and extractability, and also the third phase formed in the extraction systems were discussed primarily based on the experimental data.
Keywords:monoamide   uranyl nitrate   extracted species   structure   charaterization
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