| 由乙氧基铅配合物制备纳米PbO |
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| 引用本文： | 朱传高,王凤武,褚道葆. 由乙氧基铅配合物制备纳米PbO[J]. 无机化学学报, 2007, 23(2): 335-338 |
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| 作者姓名： | 朱传高 王凤武 褚道葆 |
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| 作者单位： | 1. 淮南师范学院化学系,淮南,232001
2. 安徽师范大学有机化学研究所,芜湖,241000 |
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| 基金项目： | 安徽省自然科学基金;淮南师范学院科研重点项目 |
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| 摘 要： | Lead complex was directly synthesized by electrochemical dissolution of lead in a cell without separating the cathode and anode. The product was characterized by FTIR, Raman spectra and 1H NMR. The xerogel was prepared by a direct sol-gel of the electrolyte solution and then dryness of it. The xerogel was heated at 450 ℃ for 2 h to obtain the nano-PbO powder. FTIR, XRD, and TEM were used to investigate the structure of nano-PbO. The results show that the lead complex is Pb(OEt)2(acac)2, which contains acac- group and could prevent the precursor from hydrolysis and sintering during the calcinations process. The nano-PbO of 20～30 nm was thus obtained in a high purity by drying at 450 ℃.
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| 关 键 词： | 电解； 乙氧基铅配合物； 溶胶-凝胶； 纳米PbO |
| 文章编号： | 1001-4861(2007)02-0335-04 |
| 修稿时间： | 2006-09-14 |
Preparation of Nano-PbO from Ethoxy-lead Complex |
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| ZHU Chuan-Gao,WANG Feng-Wu and CHU Dao-Bao. Preparation of Nano-PbO from Ethoxy-lead Complex[J]. Chinese Journal of Inorganic Chemistry, 2007, 23(2): 335-338 |
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| Authors: | ZHU Chuan-Gao WANG Feng-Wu CHU Dao-Bao |
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| Affiliation: | Department of Chemistry, Huainan Normal College, Huainan, Anhui 232001,Department of Chemistry, Huainan Normal College, Huainan, Anhui 232001 and Institute of Organic Chemistry, Anhui Normal University, Wuhu, Anhui 241000 |
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| Abstract: | |
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| Keywords: | electrolysis ethoxy-lead complexes Sol-gel, Nano-PbO |
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