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Fluordiazadiphosphetidine, 15. Mitt.: Die Reaktionen von Hexafluordiazadiphosphetidinen mit Fluorwasserstoff
Authors:Hahn  Heinrich  Meindl  Wolfgang  Utvary  Kurt
Institution:(1) Institut für Anorganische Chemie, Technische Universität Wien, A-1060 Wien, Österreich
Abstract:The reaction of fluorodiazadiphosphetidines with dry hydrogenfluoride has been studied thoroughly. Depending on the nature of the substitutents on the nitrogen atom this reaction can take two different courses: a) yielding the octafluoro-1,3,2lambda6,4lambda6-diazoniadiphosphatetidines1; b) forming the corresponding amine-phosphoruspentafluoride-adducts, which are enabled for various further reactions. A scheme of possible reactions has been established.
Keywords:Aza  Cyclic (non-carbon)  Heterocyclic (N  P)  Phospha  Zwitter ion  amine-phosphoruspentafluoride-adducts
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