Fluordiazadiphosphetidine, 15. Mitt.: Die Reaktionen von Hexafluordiazadiphosphetidinen mit Fluorwasserstoff |
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Authors: | Hahn Heinrich Meindl Wolfgang Utvary Kurt |
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Institution: | (1) Institut für Anorganische Chemie, Technische Universität Wien, A-1060 Wien, Österreich |
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Abstract: | The reaction of fluorodiazadiphosphetidines with dry hydrogenfluoride has been studied thoroughly. Depending on the nature of the substitutents on the nitrogen atom this reaction can take two different courses: a) yielding the octafluoro-1,3,2 6,4 6-diazoniadiphosphatetidines1; b) forming the corresponding amine-phosphoruspentafluoride-adducts, which are enabled for various further reactions. A scheme of possible reactions has been established. |
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Keywords: | Aza Cyclic (non-carbon) Heterocyclic (N P) Phospha Zwitter ion amine-phosphoruspentafluoride-adducts |
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