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Technische Verfahren zur Synthese von Carotinoiden und verwandten Verbindungen aus 6-Oxo-isophoron. VI. Synthese Von Rhodoxanthin und (3-RS, 3′RS)-Zeaxanthin; Zugänge zur C15-Ringkomponente über 3-Oxo-jonon-Derivate
Authors:Erich Widmer  Milan Soukup  Reinhard Zell  Emil Broger  Bruno Lohri  Roman Marbet  Teodor Luk
Institution:Erich Widmer,Milan Soukup,Reinhard Zell,Emil Broger,Bruno Lohri,Roman Marbet,Teodor Lukáč
Abstract:Technical Procedures for the Synthesis of Carotenoids and Related Compounds from 6-Oxo-isophorone, VI. Synthesis of Rhodoxanthin and (3RS, 3′RS)-Zeaxanthin; Routes to the C15-Ring Component via 3-Oxo-ionone Derivatives The C15-ring component 4 , key intermediate of a new scheme for the synthesis of rhodoxanthin ( 1 ) and (3RS, 3RS)-zeaxanthin ( 3 ), has been synthesized starting from 6-oxo-isophorone ( 7 ) via 3-oxo-cyclocitral and 3-oxo-ionone derivatives.
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