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Some stereochemical effects in gaseous ion decompositions
Authors:A Mahender Reddy  M S B Nayar  G Sudhakar Reddy  K G Das
Abstract:Stereochemical effects were observed in the electron ionization, methane, isobutane and ammonia positive ion chemical ionization and hydroxy negative ion chemical ionization behaviour of some isomeric triaryl nitrocyclohexenes. cis-Eliminations leading to loss of HNO2, H2NO2 and arene were found to be stereochemically preferred in gaseous ions.
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