Abstract: | Metal Complexes of Phosphinic Acids. XVIII. Ansa- and Oligo-Complexes of Bifunctional Dithiophosphinic Acids The influence of R′ in the bifunctionell chelate ligands ?S(S)P(R)? R′? (R)P(S)S? on the association of their planar NiII and tetrahedral CoII complexes is investigated by vapour pressure osmometry and in the case of diamagnetic NiII compounds also by 31P-NMR spectroscopy. While insoluble coordination polymers S2P(R)? R′? (R)PS2M]x (M = NiII, CoII) are formed with R′ = p-(C2H4)2C6H4 it can be shown, that in solutions of the complexes with R′ = o-(C2H4)2C6H4 and R′ = o-(C3H6)2C6H4 there exists an association equilibrium comprehending oligomers with n ? x. Above all in the latter case steric conditions seem to favour intramolecular chelating and thus formation of ansa-type complexes. Synthesis of the ligands and the complexes is described. |