Dimer formation in methane chemical ionization mass spectrometry of organic functionalities,including 2-azaadamantane derivatives |
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Authors: | Massimo D Bezoari Peter Kovacic Andr R Gagneux |
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Institution: | Massimo D. Bezoari,Peter Kovacic,André R. Gagneux |
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Abstract: | The methane chemical ionization mass spectra of 1-hydroxy-2-azaadamantane, its lactolactam, and 1-chloro-2-azaadamantanes exhibit high intensity dimeric species. These correspond to 2M+H]+ or stable fragments formed via gas phase chemical reactions, such as dehydration (aminol case) or dehydrohalogenation (chloroazaadamantanes). The tert-amino chloroazaadamantane forms a stable 2M+C2H5]+ ion with much higher intensity than the 2M+H]+ ion. Similar dimeric species were observed with simple functionalities, including amide, amine, alcohol and alkene. Pressure, temperature and, apparently, steric effects play important roles. Structures are proposed for the various dimeric ions. |
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