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Gas‐phase pyrolysis in organic synthesis. Part 3: Novel cyclization of 2‐arylhydrazonopropanals into cinnolines1
Authors:Ajith Kumar  Nouria A Al‐Awadi  Mohamed H Elnagdi  Yehia A Ibrahim  Kamini Kaul
Abstract:3‐oxo‐3‐aryl‐2‐arylhydrazonopropanals (1) have been converted under thermal gas‐phase conditions cleanly into cinnolines (2) . A plausible mechanism is suggested to account for this transformation based on the kinetics and products of reaction. © 2001 John Wiley & Sons, Inc. Int J Chem Kinet 33: 402–406, 2001
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