Formation and Molecular Structure of an Ion Pair Iron (II) Compound Derived from 2,6‐Bis‐ [1‐(2,6‐dibromophenylimino) ‐ethyl] pyridine and 2‐Acetyl‐6‐[1‐(2, 6‐dibromophenylimino)‐ethyl] pyridine |
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Authors: | Rui‐Fang Chen Chang‐Tao Qian Jie Sun |
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Abstract: | Two novel tridentate ligands of 2,6‐bis‐[l‐(2,6‐dibromophenylimino) ethyl] pyridine (L1) and2‐acetyl‐6‐[1‐(2,6‐dibromophenylimino) ethyl] pyridine (L2) have been synthesized. The iron(II) complex of L1 and L2 has been characterized with the crystal structure of [Fe(L1)(L2)]2+ [FeCl4]2 CH2Cl2 [monoclinic, P21 (#11), a = 1.0562(4), b = 2.0928(4), c = 1.2914(2) nm, β = 100.12°, V = 2.810(1) nm3 Dc = 1.879 g/cm3 and Z = 2]. |
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Keywords: | Fe(II) complex 2,6‐bis[1‐(2,6‐dibromophenylimino) ethyl] pyridine 2‐acetyl‐6‐[l‐(2 6‐dibromophenylimino)‐ethyl] pyridine |
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