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Sm°/Cat. I2 and SmI2 induced reductive coupling of nitriles with azides |
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| Authors: | Wei‐Ke Su Yong‐Shu Li Yong‐Min Zhang |
| Abstract: | The intermolecular reductive coupling of nitriles with azides induced by Sm°/Cat. I2 or SmI2 was studied. Aromatic and aliphatic amidines were prepared in moderate to good yields under neutral and mild conditions respectively. |
| Keywords: | Samarium diiodide Sm0/Cat. I2 system amidine reductive coupling azide nitrile |