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The Synthesis of N‐(Glycosylthioureylene)‐aminothiophosphonic and ‐diaminothiophosphinic O‐aryl Esters |
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| Authors: | Ling‐Hua Cao Chuan‐Jian Zhou Hong‐Yun Gao Yu‐Ting Liu |
| Abstract: | Reactions of O‐aryl dihydrazinothiophosphinates ( 4, 5 ) or O,O′‐diarylhydrazinothio‐phosphonates ( 2 ) with glycosyl isocyanates ( 6 ) gave corresponding N‐(glycosylthioureylene)‐aminothiophosphonic and ‐diaminothiophosphinic O‐aryl esters. Their structures were confirmed by IR, 1H NMR, 31P NMR, MS and elemental analyses. |
| Keywords: | Glycosyl isothiocycanates Aminothio‐phosphonic ester Diaminothiophosphinic ester Synthesis |