Solid‐State NMR Study on Relationships between Miscibility and Chain Mobility in Poly(4‐Methylstyrene)/Poly(Cyclohexyl Methacrylate) Blend

The phase behavior and motional mobility in binary blends of poly(4‐methylstyrene) (P4MS) and poly(cyclohexyl methacrylate) (PCHMA) have been examined by ¹³C solid state NMR techniques. The blend miscibility was studied by measuring the ¹H spin‐relaxation times in the laboratory frame (T₁^H) and in the rotating frame (T_1ρ^H), respectively. Although intermolecular spin diffusion contributes to the proton relaxations in accordance with homogeneity, T_1ρ^H data shows signs of in complete averaging. The T_1ρ^H relaxation behavior indicates the existence of heterogeneous do mains with shortest dimensions in the nanometer range, which is also sup ported by the intermolecular cross polarization experiments with variable contact times. In addition, according to the resuits of carbon T_1ρ relaxation time measurements, it is concluded that mixing is intimate some what enough to cause a reduction in local chain mobility for P4MS and vice versa for PCHMA.