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Five-membered 2,3-dioxo heterocycles: LVII. Recyclization of 3-pivaloylpyrrolo[1,2-a]quinoxaline-1,2,4(5H)-triones by the action of o-phenylenediamine. Crystalline and molecular structure of 3-[3,3-dimethyl-2-oxo-1-(3-oxo-3,4-dihydroquinoxalin-2-yl)butyl]-1-phenylquinoxalin-2(1H)-one
Authors:K. S. Bozdyreva   Z. G. Aliev  A. N. Maslivets
Affiliation:(1) Perm State University, ul. Bukireva 15, Perm, 614990, Russia;(2) Institute of Chemical Physics Problems, Russian Academy of Sciences, Chernogolovka, Moscow oblast, Russia
Abstract:3-[(Z)-3,3-Dimethyl-2-oxobutylidene]-3,4-dihydroquinoxalin-2(1H)-one and its 1-phenyl-substituted analog reacted with oxalyl chloride to give the corresponding 3-pivaloylpyrrolo[1,2-a]quinoxaline-1,2,4(5H)-triones. Reactions of the latter with o-phenylenediamine led to the formation of 3,3′-(3,3-dimethyl-2-oxobutane-1,1-diyl)di[quinoxalin-2(1H)-ones]. Original Russian Text ? K.S. Bozdyreva, Z.G. Aliev, A.N. Maslivets. 2008, published in Zhurnal Organicheskoi Khimii, 2008, Vol. 44, No. 4, pp. 612–616. For communication LVI, see [1].
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