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Correlation entropy in a classical liquid
Affiliation:1. New College of Florida, Sarasota, Florida, USA;2. Technical University of Cologne, Cologne, Germany;3. University of Applied Sciences, Darmstadt, Germany
Abstract:A statistical formula is presented for the entropy of a classical monatomic liquid, including effects of multiparticle correlations. This theory applies to the liquid state, which has small density fluctuations, and which is distinct from the gas state. The statistical entropy is found to agree well with the thermodynamic entropy for liquid sodium at temperatures from 378 to 823 K.
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