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Structure of 2-acetoxy-1,2-di(1-adamantyl)ethanone
Authors:Simon G Bott  Alan P Marchand  Angela R McGuffey  Dongxia Xing
Institution:(1) Department of Chemistry, University of North Texas, 76203 Denton, Texas
Abstract:The structure of 2-acetoxy-1,2-di(1-adamantyl)ethanone is reported. The steric requirements of the two adamantyl groups affect the structure in three ways—a slight elongation of the central bond, a small expansion of the angles about the central bond, and a conformation in which the C(sp2)-connected adamantyl group virtually bisects the large substituents attached to the sp3 carbon.
Keywords:Crystal structure  1  2-di(1-adamantyl)ethene
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