Oxidation of prochiral sulfides with chiral dioxirane |
| |
| Authors: | S A Dieva R M Eliseenkova Yu Ya Efremov D R Sharafutdinova A A Bredikhin |
| |
| Institution: | (1) Arbuzov Institute of Organic and Physical Chemistry, Kazan Research Center, Russian Academy of Sciences, ul. Arbuzova 8, Kazan, 420088, Tatarstan, Russia |
| |
| Abstract: | Dioxirane generated in situ by reaction of chiral 1,2:4,5-di-O-isopropylidene-D-erythro-hexo-2,4-diulo-2,6-pyranose with Oxone oxidizes prochiral sulfides to the corresponding sulfoxides with an enantiomeric excess of 2 to 25%. |
| |
| Keywords: | |
| 本文献已被 SpringerLink 等数据库收录！ |
|
