| Pd催化的需氧氧化反应的新进展 |
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| 引用本文： | 王嘉瑞,邓维,王晔峰,刘磊,郭庆祥.Pd催化的需氧氧化反应的新进展[J].有机化学,2006,26(4):397-412. |
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| 作者姓名： | 王嘉瑞 邓维 王晔峰 刘磊 郭庆祥 |
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| 作者单位： | 中国科学技术大学化学系,合肥,230026 |
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| 摘 要： | 总结了近年来对Pd催化的需氧氧化反应研究的最新进展, 包括醇的氧化反应和对二级醇的氧化动力学手性拆分, 烯烃的氧化反应, 氧化脱氢性C—O, C—N和C—C成键反应、以及C—C键键裂产生的开环、扩环、缩环反应. 另外, 对反应中涉及的机理研究也进行了详细的描述.
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| 关 键 词： | Pd 催化剂 需氧氧化 氧气 动力学拆分 |
| 收稿时间： | 01 10 2005 12:00AM |
| 修稿时间： | 05 25 2005 12:00AM |
New Advances in Palladium-Catalyzed Aerobic Oxidations |
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| WANG,Jia-Rui,DENG,Wei,WANG,Ye-Feng,LIU,Lei,GUO,Qing-Xiang.New Advances in Palladium-Catalyzed Aerobic Oxidations[J].Chinese Journal of Organic Chemistry,2006,26(4):397-412. |
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| Authors: | WANG Jia-Rui DENG Wei WANG Ye-Feng LIU Lei GUO Qing-Xiang |
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| Institution: | Department of Chemistry, University of Science and Technology of China, Hefei 230026 |
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| Abstract: | New advances in palladium-catalyzed aerobic oxidation reactions are reviewed. The reactions include aerobic oxidation of alcohol, kinetic resolution of secondary alcohols, oxidation of alkenes, oxidative C-O, C-N and C-C bond formation reactions, oxidative ring opening, expansion and contracting reactions. In addition, the mechanisms of these novel reactions are discussed in detail |
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| Keywords: | palladium catalyst aerobic oxidation molecule oxygen kinetic resolution |
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