| 描述自旋体系密度算符演化的新方法 |
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| 引用本文： | 林东海,吴钦义.描述自旋体系密度算符演化的新方法[J].物理学报,1993,42(6):893-904. |
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| 作者姓名： | 林东海 吴钦义 |
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| 作者单位： | 厦门大学化学系,厦门361005;中国科学院武汉物理研究所,武汉430071;厦门大学化学系,厦门361005 |
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| 摘 要： | 提出一种描述自旋体系密度算符演化的新方法,可统一处理核磁共振波谱学中强、弱偶合自旋体系及弱射频场存在下密度算符的演化。具体分析一些核磁共振实验:自旋轻扰、自旋锁定、偶极耦合作用、强耦合AB和ABX自旋体系的演化。
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| 关 键 词： | 自旋体系 密度算符 演化 NMR |
| 收稿时间： | 1992-08-18 |
A NEW FORMALISM FOR DESCRIBING THE EVOLUTION OF DENSITY OPERATORS |
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| LIN DONG-HAI and WU QIN-YI.A NEW FORMALISM FOR DESCRIBING THE EVOLUTION OF DENSITY OPERATORS[J].Acta Physica Sinica,1993,42(6):893-904. |
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| Authors: | LIN DONG-HAI and WU QIN-YI |
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| Abstract: | A new formalism for describing the evolution of density operators was proposed. It can evaluate the evolution of density operators of strongly and weakly coupled spin systems in a u-nified way, and describe the experiments involving weak RF pluse. Some problems were explicitly treated including spin tickling, isotropic mixing in systems of two coupled nuclei (I= 1/2), dipolar evolution and strongly coupled AB and ABX spin systems. |
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