Kinetic study of nickel(II) complexation by pteroylglutamic acid |
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Authors: | Thomas Andre´s Wolcan Ezequiel Fe´liz Mario R Capparelli Alberto L |
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Institution: | 1. Instituto de Investigaciones Fisicoqui′micas Teo′ricas y Aplicadas (INIFTA), Facultad de Ciencias Exactas, Universidad Nacional de La Plata, Casilla de Correo 16, Sucursal 4, (1900), La Plata, Repu′blica Argentina
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Abstract: | The kinetics of the complexation of NiII by pteroylglutamic acid have been studied in the 545 ∘C range, the ionic strength
(0.6 M) being regulated with KNO3, in the 5.5–7.0pH range, using the stopped-flow method. Under the experimental conditions
two processes were observed. The faster process was detected in the millisecond range and is associated with the reaction
between NiII and the ligand. The slower is observed within a few seconds. Complementary equilibrium studies were made at 25
∘C. The results are consistent with the formation of a 1:1 complex between the reactants, and a mechanism is proposed to account
for the observed behaviour. Equilibrium constants for the NiII plus pteroylglutamic acid system, as well as activation parameters,
are reported.
This revised version was published online in June 2006 with corrections to the Cover Date. |
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